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Neymar and the Brazil team arrive in Chile. / Rafael Ribeiro - CBF

FC Barcelona's Dani Alves and Neymar make their Copa America 2015 on Sunday at 11.30pm CET, as the Canarinha, with Dunga as their new coach, begin their quest for the continental title.

The duel between Brazil and Peru is the second match of Group C on Sunday, as Colombia and Venezuela also face off. Neymar is Brazil's captain and top striker, while right-back Dani Alves was called at the last minute following an injury to Danilo.

When Dani Alves and Neymar take the field they will be the fourth and fifth Barça players to do so at this year's Copa América. Goalkeeper Claudio Bravo played for Chile in their 2–0 win over Ecuador, while Argentines Lionel Messi and Javier Mascherano played in their team's 2–2 draw with Paraguay.

Here is Brazil's calendar in Group C (All times Central European Time):

MATCH DAY TIME
Brazil v Peru 14 June 11.30pm
Brazil v Colombia 18 June 2.00am
Brazil v Venezuela 21 June 11.30pm
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